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Graphite, the most stable form of elemental carbon, consists of pure carbon sheets stacked upon one another like reams of paper. Individual sheets, known as graphene, prefer planar geometries as a consequence of the hexagonal honeycomb-like arrangements of trigonal carbon atoms that comprise their two-dimensional networks. Defects in the form of non-hexagonal rings in such networks cause distortions away from planarity. Herein we report an extreme example of this phenomenon. A 26-ring C80H30 nanographene that incorporates five seven-membered rings and one five-membered ring embedded in a hexagonal lattice was synthesized by stepwise chemical methods, isolated, purified and fully characterized spectroscopically. Its grossly warped structure was revealed by single-crystal X-ray crystallography. An independent synthetic route to a freely soluble derivative of this new type of 'nanocarbon' is also reported. Experimental data reveal how the properties of such a large graphene subunit are affected by multiple odd-membered-ring defects.


Kawasumi, K.; Zhang, Q.; Segawa, Y.; Scott, L. T.; Itami, K. Nat Chem 2013, advance online publicationContributed by Steven Bachrach.Reposted from Computational Organic Chemistry with permissionScott and Itami report on a graphene fragment that is highly warped.1 They...
Scott and Itami report on a graphene fragment that is highly warped.1 They have prepared 1 by three separate procedures, one of which starts with corranulene and in two steps makes the product!1The five 7-member rings warp the structure so that it is non-planar....
A new form of carbon: Grossly warped 'nanographene' - Chemists at Boston College and Nagoya University in Japan have synthesized the first example of a new form of carbon, the team reports in the most recent online edition of the journal Nature Chemistry.[1]References...